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Background on Potassium Permanganate

Potassium permanganate (KMnO4) is a strong oxidizing agent that was originally discovered in 1659. Carus Corporation has been producing permanganate since 1915. As an oxidizing agent it has the ability to add oxygen, remove hydrogen or remove electrons from an element or compound. Potassium permanganate is made up of 1 manganese atom surrounded by 4 oxygen atoms. The molecular weight of permanganate is 158.04 g/mol. The diagram below is of a permanganate tetrahedral.

Molecular Diagram of Potassium Permanganate

Potassium permanganate has the ability to “oxidize” soluble manganese and iron in drinking water to an insoluble manganese dioxide and iron oxide that can be removed by filtration. If these compounds were left untreated, they would cause staining of plumbing fixtures such as toilets, sinks and bath tubs and impart a bad taste to the water.



Potassium permanganate is recognized by its characteristic purple to pink color when made into a solution. In high concentrations it is a dark purple color.

Different Concentrations  of Potassium Permanganate

The picture above demonstrates this color with permanganate concentrations ranging from 0.5 to 100 parts per million (ppm).

CAIROX ® Potassium Permanganate has been used in many applications over the years from drinking water treatment to pharmaceutical manufacture. In drinking water treatment, CAIROX ® is used to oxidize iron, manganese, hydrogen sulfide, arsenic, to improve taste and odor and is used as a preoxidant for disinfection by-product control. CAIROX® can help to produce high quality water and to meet strict drinking water standards. In pharmaceutical applications it has been used to oxidize functional groups, such as aromatic side chains to carboxylic acids, organic sulfides to sulfones and to produce antibiotics and tranquilizers.


CARULITE® (Hopcalite Type Catalysts)  ·   U.S. Feed Systems  ·   Hazardous Remediation with ISCO  ·   Industrial Applications  ·   Municipal Drinking Water Treatment  ·   Reducing Manganese in Water  ·   In Situ Stabilization ISBS  ·   Taste and Odor Control  ·   Pre-Oxidation  ·   Reducing Hydrogen Sulfide in Water  ·   Mercaptan Odor Control  ·   Wastewater Odor Control  ·   Sludge Dewatering Facility  ·   Trihalomethanes (THM) Control  ·   Industrial Wastewater Treatment  ·   Industrial Water Purification  ·   Municipal Applications - Phosphates  ·   Corrosion Control  ·   Sequestering Agents  ·   Lead Contamination in Water  ·   Organic Oxidation / Fine Chemicals  ·   Curing Grade Manganese Dioxide (MnO2)  ·   Lithium Manganese Spinel  ·   Biofilm Control  ·   Ozone Air Purification